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The element of surprise Run to Daylight, p 112 If you can be traded Coach, p 285 A professional football team Run to Daylight, p 55

Upon rearrangement, this may be written:

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Equation (1620) for the molar entropy of an ideal gas allows calculation of absolute entropies for the ideal-gas state The data required for evaluation of the last two terms on the right are the bond distances and bond angles in the molecules, and the vibration frequencies associated with the various bonds, as determined from spectroscopic data The procedure has been very successful in the evaluation of ideal-gas entropies for molecules whose atomic structures are known Both the classical and statistical equations [Eqs (540) and (1620)] yield absolute values of entropy As is evident from Table 163,12good agreement between the statistical calculations and those based on calorimetric data is obtained Results such as these provide impressive evidence for the validity of statistical mechanics and quantum theory In some instances results based on Eq (1620) are considered more reliable because of uncertainties in heat-capacity data or about the crystallinity of the substance near absolute zero Absolute entropies provide much of the data base for calculation of the equilibrium conversions of chemical reactions, as discussed in Chap 13

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his mathematical development is lengthy but not unduly difficult An elementary treatment is given by H C Van Ness, Understanding Thermodynamics, chap 7 , McGraw-Hill, New York, 1969; Dover, New York, 1983 Much more comprehensive are D A McQuarrie, Statistical Mechanics, Harper & Row, New York, 1976, and R L Rowley, Statistical Mechanics for Thermophysical Property Calculations, PTR Prentice Hall, Englewood Cliffs, NJ, 1994

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Conquests are won From Vince Lombardi s 6/22/70 Dayton speech This is not easy Run to Daylight, p 88 It s no damn fun Coach, p 314 I am going to find Vince, p 143 I m just going to Vince, p 249 All right, barked my father Plimpton, George One More July Harper & Row: New York, 1977, pp 24 26 Perhaps you didn t realize When Pride Still Mattered, p 265 There is a time Strive to Excel, p 24 What was that all about When Pride Still Mattered, p 394 It took the edge off the tension Vince, p 245 The truth is, halfback Donny Anderson From an unidentified newsclip in Vince Lombardi, Jr s files You can t coach The Lombardi Method [Jordan] has a tendency Run to Daylight, p 70 I walked into his office Lombardi, p 180 It s the motivation that s the thing Lombardi, p 171 I hold it more important Winning is a Habit, p 106 When I think of him Vince, p 351 There are some people Coach, p 314 Changes take time From an undated Vince Lombardi talk entitled Goal Posts, in Vince Lombardi Jr s collection The achievements of an Strive to Excel, p 83

Eq (540) Eq (1620)

40 10 14

The fundamental property relation most intimately connected with statistical mechanics is Eq (69), which expresses the differential of the Helmholtz energy as a function of its canonical variables T and V:

d A = -PdV - SdT (69) We remarked in connection with Eq (1613) that the partition function Z is a state function from which all thermodynamic properties may be found once it is known as a function of T and V Its relation to the Helmholtz energy follows from Eq (1619), which may be written:

He was tough and abusive Vince, p 247 The shoutings, encouragements From an undated letter in Vince Lombardi, Jr s collection from Starr to Vince Lombardi

Reference to Eq (62) shows that the left side of this equation is by definition the Helmholtz energy A Therefore,

(B) 16 10 (C) (D)

This equation provides a direct link between thermodynamics and statistical mechanics Since R = k N A , where NA is Avogadro's number, Eq (1621) may be expressed alternatively as:

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